Mathur, Pradeep ; Munkir Hossain, Md. ; Rashid, Raad S. (1993) Trinuclear and tetranuclear iron/ruthenium carbonyl clusters stabilized by bridging selenium ligands Journal of Organometallic Chemistry, 460 (1). pp. 83-86. ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002232...
Related URL: http://dx.doi.org/10.1016/0022-328X(93)80361-E
Abstract
At room temperature, Fe2(CO)6(μ-Se2) reacts with Ru3(CO)12 to form Fe2Ru3(CO) 17( (μ4-Se)(μ3-Se), and with Ru(CO)4(C2H2) to form Fe2Ru(CO)9(μ3-Se)2. The latter reacts with Fe(CO)5 under visible light irradiation to give Fe3Ru(CO)11(μ4-Se)2, and with Ru(CO)4(C2H4) to form Fe2Ru2(CO)11(μ4-Se)2. Visible light irradiation of a solution containing Fe3(CO)9(μ3-Se)2 and Fe(CO)5 yields Fe4(CO)11(μ4-Se)2. A solution containing Fe3(CO)9(μ3-Se)2 and Ru(CO)4(C2H4) at room temperature with stirring yielded Fe3Ru(CO)11(μ4-Se)2.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 24839 |
| Deposited On: | 01 Dec 2010 12:40 |
| Last Modified: | 01 Dec 2010 12:40 |
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