Kumar, Sarvesh ; Peruncheralathan, Saravanan ; Ila, Hiriyakkanavar ; Junjappa, Hiriyakkanavar (2008) A novel anionic domino process for the synthesis of o-cyanoaryl-methylthio/alkyl/aryl/heteroaryl acetylenes Organic Letters, 10 (5). pp. 965-968. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol800029c
Related URL: http://dx.doi.org/10.1021/ol800029c
Abstract
A novel unexpected anionic domino process involving n-BuLi-induced rearrangement of 3,3-bis(methylthio) or 3-methylthio-3-aryl/heteroaryl/alkyl-o-bromoarylacrylonitriles to o-cyanoarylacetylenes in synthetically useful yields has been reported. The scope and generality of the reaction has been examined, and a possible mechanism has been proposed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 24052 |
| Deposited On: | 29 Nov 2010 10:32 |
| Last Modified: | 22 Feb 2011 04:49 |
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