Photoinduced reaction of perchlorocyclopentadiene with Mn2(CO)10

Chaudhuri, Mihir Kanti (1979) Photoinduced reaction of perchlorocyclopentadiene with Mn2(CO)10 Journal of Organometallic Chemistry, 171 (3). pp. 365-367. ISSN 0022-328X

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...

Related URL: http://dx.doi.org/10.1016/S0022-328X(00)82660-1

Abstract

Perchlorocyclopentadiene, C5Cl6, and Mn2(CO)10 produce C5Cl5., Cl. and (CO)5Mn. radicals upon UV-irradiation, and these then react among themselves to give ultimately Mn(η 1-C5Cl5)(CO)5, Mn(CO)5Cl, and C10Cl10. The products were characterised by elemental analysis, IR and mass spectral studies. The mass spectrum of pentacarbonyl(η 1-pentachlorocyclopentadienyl)manganese is discussed.

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