Direct synthesis of tris(acetylacetonato)manganese(III)

Bhattacharjee, Manabendra N. ; Chaudhuri, Mihir K. ; Khathing, Darlando T. (1982) Direct synthesis of tris(acetylacetonato)manganese(III) Journal of the Chemical Society, Dalton Transactions (3). pp. 669-670. ISSN 0300-9246

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Official URL: http://www.rsc.org/publishing/journals/DT/article....

Related URL: http://dx.doi.org/10.1039/DT9820000669

Abstract

A concentrated solution of K[MnO4] undergoes a ready reaction with acetylacetone, in the absence of any buffer, giving a very high yield of the title compound, [Mn(acac)3]. The pH of the solution, recorded immediately after the formation of crystalline [Mn(acac)3], was found to be ca. 5. Electron impact induced mass spectrometry showed the compound to be monometric.

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