Potassium trifluoroperoxotitanate(IV) trihydrate, K[Ti(O2)F3] . 3H2O

Chaudhuri, M. K. ; Das, B. (1985) Potassium trifluoroperoxotitanate(IV) trihydrate, K[Ti(O2)F3] . 3H2O Polyhedron, 4 (8). pp. 1449-1450. ISSN 0277-5387

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S02775...

Related URL: http://dx.doi.org/10.1016/S0277-5387(00)86979-X

Abstract

Potassium trifluoroperoxotitanate(IV) trihydrate, K[Ti(O2)F3] . 3H2O, with the peroxide (O22-) being bonded to the Ti(IV) centre in a triangular bidentate manner (C2v) as evidenced from the IR and laser Raman spectroscopic studies, has been synthesised from the reaction of a solution of TiO2in 40% HF with an excess of 30% H2O2 and KOH, followed by the addition of aqueous HF to adjust the pH of the reaction solution between 8 and 9.

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