First reported synthesis of ammonium hexafluorodioxouranate(VI), (NH4)4[UO2F6]

Chaudhuri, Mihir K. ; Khathing, Darlando T. ; Srinivas, Pendyala (1992) First reported synthesis of ammonium hexafluorodioxouranate(VI), (NH4)4[UO2F6] Journal of Fluorine Chemistry, 56 (3). pp. 305-307. ISSN 0022-1139

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00221...

Related URL: http://dx.doi.org/10.1016/S0022-1139(00)81177-X

Abstract

Bis(acetylacetonato)dioxouranium(VI) dihydrate, UO2(C5H7O2)2.2H2O, reacts with NH4F in the presence of an excess of acetylacetone and a trace of water to produce (NH4)4[UO2F6] in high yield. The results of chemical analyses, molar conductance, IR and laser Raman spectroscopic studies have been used for characterisation of the compound.

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