Absorption spectrum of the HCCO radical

Krishnamachari, S. L. N. G. ; Venkatasubramanian, R. (1984) Absorption spectrum of the HCCO radical Pramana - Journal of Physics, 23 (3). pp. 321-325. ISSN 0304-4289

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Official URL: http://www.ias.ac.in/j_archive/pramana/23/3/321-32...

Related URL: http://dx.doi.org/10.1007/BF02846575


In the flash-photolysis of oxazole and isoxazole, new transient absorption bands are observed in the region 3080-3670Å. Vibrational analysis of these bands showed that they can be arranged into two electronic systems with their origin bands at 3333.60Å and 3367.01Å. Based on the experimental conditions under which the bands are produced and on the analysis of their vibrational and gross-rotational structure, these bands are assigned to a new carrier, the HCCO free radical.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
Keywords:Hcco Radical Optical Absorption Spectrum; Oxazole; Isoxazole Flash-photolysis
ID Code:23360
Deposited On:25 Nov 2010 09:11
Last Modified:17 May 2016 07:12

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