Structure-function relationship in some macrocyclic dicopper complexes

Nag, K. (1990) Structure-function relationship in some macrocyclic dicopper complexes Proceedings of the Indian Academy of Sciences - Chemical Sciences, 102 (3). pp. 269-282. ISSN 0253-4134

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A number of macrocyclic dicopper(II) complexes containing aza-, amino or amido nitrogen and phenolic oxygen donors are described, X-ray crystal structures of several of these compounds are discussed. An account of their electrochemical behaviour and magnetic properties is given. Factors that affect electron transfer behaviour with regard to stabilization of the lso- and mixed-valence species, intramolecular electron transfer, and spin-exchange interactions have been examined in terms of the structural features.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
Keywords:Macrocyclic Dicopper Complexes; X-ray Structure; Electrochemistry; Magnetic Properties
ID Code:22729
Deposited On:24 Nov 2010 07:57
Last Modified:17 May 2016 06:42

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