Thermal and crystallization behavior of engineering polyblends. I. Glass reinforced polyphenylene sulfide with polyethylene terephthalate

Abstract

The thermal and crystallization behavior of blends of glass fiber reinforced polyphenylene sulfide (PPS) with polyethylene terephthalate (PET) has been reported. The blends showed two overlapping melting peaks and two separate crystallization peaks. The heat of crystallization of PPS was found to decrease continuously with increasing PET content, whereas the heat of crystallization of PET was found to increase with increasing PPS content. This indicates that the degree of crystallinity of PPS is reduced whereas that of PET is increased as a result of blending. It is interesting to note that the combined heats of fusion of the blends were marginally higher than those calculated by proportional additivity rule in spite of the drop in the heat of crystallization of PPS. The temperature onset of crystallization of PET in the blends shifted to higher temperature whereas there was no significant change in the crystallization temperature of PPS. The increase in the temperature of crystallization of PET indicates enhanced nucleation. The isothermal crystallization studies of the component polymers revealed that both the component polymers crystallized at a relatively faster rate in the blend. The crystallization rate of PPS was found to increase significantly with increasing PET content. A significant increase in the rate of crystallization of PET was also observed in the blends. The acceleration of crystallization rate of PET in the blends was more pronounced as compared to that of PPS. The acceleration in the PET crystallization rate was attributed to the presence of glass fibers and crystallized PPS.