Hydrodynamic shielding induced stability of zipping macromolecules in elongational flows

Abstract

Enhanced shear stability of associating polymers during drag reduction observed recently has been attributed to the breakage of reversible associations (e.g., hydrogen bonds) in preference to covalent bonds in the polymer backbone. A simple mechanistic analysis of a perfectly "zipped" assembly of fully extended bead rod chain model of two macromolecules in steady elongational flow is presented. It explains the enhanced stability as a result of (i) distribution (near the vulnerable chain center) of the drag tension into the two parallel "zipped" chains, and (ii) reduction of the drag force due to the enhanced hydrodynamic shielding. Some guidelines for optimum design of shear stable and effective drag reducing macromolecules have been deduced.