Connected-diagram expansions of effective Hamiltonian in incomplete model spaces. II. General incomplete model spaces

Mukherjee, Debashis ; Kutzelnigg, Werner ; Koch, Sigurd (1987) Connected-diagram expansions of effective Hamiltonian in incomplete model spaces. II. General incomplete model spaces Journal of Chemical Physics, 87 (10). 5911_1-5911_6. ISSN 0021-9606

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Official URL: http://link.aip.org/link/?JCPSA6/87/5911/1

Related URL: http://dx.doi.org/10.1063/1.453514

Abstract

We generalize here the formalism of the preceeding paper to encompass the case of the general incomplete model space. The classification of operators as diagonal or nondiagonal depends in this case upon the specific m-valence model space. It is stressed that even then one has to work in Fock space in order to get connected-diagram expansions, since connectedness is a Fock space property. Two choices of separable normalization of the wave operator W leading to a connected Heff are discussed. It is shown that the intermediate normalization is not separable in general and hence not compatible with a connected-diagram expansion. We also discuss how to generate "subduced" incomplete model spaces of lower particle rank such that Heff remains a valid effective Hamiltonian for these subduced model spaces as well. We discuss the nature of the various disconnected diagrams encountered in many-body formalisms and point out which of these are really worth worrying about. We finally comment on the question of the separability of the wave function into proper fragments.

Item Type:Article
Source:Copyright of this article belongs to American Institute of Physics.
Keywords:Quantum Mechanics; Perturbation Theory; Many-body Problem; Hamiltonian Function; Wave Functions; Valence
ID Code:21923
Deposited On:23 Nov 2010 09:02
Last Modified:05 Mar 2011 13:05

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