Copper complexes of 1,1-di(2-pyridyl)ethyl methyl ether: X-ray crystal structures and reactions with dioxygen

Bhaduri, Sumit ; Sapre, Niteen Y. ; Jones, Peter G. (1991) Copper complexes of 1,1-di(2-pyridyl)ethyl methyl ether: X-ray crystal structures and reactions with dioxygen Journal of the Chemical Society Dalton Transactions . pp. 2539-2543. ISSN 1472-7773

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Official URL: http://www.rsc.org/publishing/journals/DT/article....

Related URL: http://dx.doi.org/10.1039/DT9910002539

Abstract

The mixed-valence complexes [CuIIL13][CuI2I4](L1= di-2-pyridyl ketone), [CuII(HL2)2][CuI2I4][HL2= 1,1-di(2-pyridyl)ethanol] and [CuIIL32][CuI2I4][L3= 1,1-di(2-pyridyl)ethyl methyl ether] have been isolated from the reactions of CuI with the respective ligands. On interactions with dioxygen the last two complexes are oxidised to [CuII2L22I2] and [CuII2L32(OH)2][CuII3] respectively. The X-ray crystal structures of [CuIIL32][CuI2I4] and [CuII2L32(OH)2][CuII3] are reported.

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Deposited On:08 Oct 2010 07:37
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