Use of isotopes for studying reaction mechanisms: 3. Secondary kinetic isotope effect

Maitra, U. ; Chandrasekhar, J. (1997) Use of isotopes for studying reaction mechanisms: 3. Secondary kinetic isotope effect Resonance - Journal of Science Education, 2 (8). pp. 18-25. ISSN 0971-8044

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Official URL: http://www.ias.ac.in/resonance/Aug1997/pdf/Aug1997...

Related URL: http://dx.doi.org/10.1007/BF02834997

Abstract

The effects of isotopic substitution on equilibrium constants and reaction rates in processes which do not directly involve the isotopic atom are described. In particular, the mechanistic details which can be obtained by quantifying the secondary kinetic isotope effect and steric isotope effect are illustrated.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
ID Code:21215
Deposited On:20 Nov 2010 09:11
Last Modified:17 May 2016 05:25

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