Unusual structural effects on the chemical degradation of steroid sidechains

Breslow, Ronald ; Maitra, Uday (1984) Unusual structural effects on the chemical degradation of steroid sidechains Tetrahedron Letters, 25 (51). pp. 5843-5846. ISSN 0040-4039

Full text not available from this repository.

Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(01)81700-7

Abstract

17-Chlorosteroids from template-directed halogenation can be converted to 17(20) olefins with DBU or DBN. The dependence of this reaction on base-structure and reaction conditions suggests geometric control by liquid packing effects related to those operating in liquid crystals.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:21189
Deposited On:20 Nov 2010 08:56
Last Modified:26 Feb 2011 10:49

Repository Staff Only: item control page