Remote functionalization on the steroid β-face: attack on an angular methyl group, and into the sidechain

Breslow, Ronald ; Maitra, Uday ; Heyer, Dennis (1984) Remote functionalization on the steroid β-face: attack on an angular methyl group, and into the sidechain Tetrahedron Letters, 25 (11). pp. 1123-1126. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(01)91539-4

Abstract

Benzophenonealkanoate esters of 6-β-cholestanes insert photolytically into C-15, C-16, and the C-18 methyl, or into C-23 and C-25 of the sidechain, depending on the length of the attaching chain.

Item Type:Article
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ID Code:21186
Deposited On:20 Nov 2010 08:55
Last Modified:26 Feb 2011 10:48

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