Selective and unusual fluoride ion complexation by a steroidal receptor using OH···F- and CH···F- interactions: a new motif for anion coordination?

Ghosh, Sanjib ; Choudhury, Angshuman Roy ; Guru Row, Tayur N. ; Maitra, Uday (2005) Selective and unusual fluoride ion complexation by a steroidal receptor using OH···F- and CH···F- interactions: a new motif for anion coordination? Organic Letters, 7 (8). pp. 1441-1444. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol047462s

Related URL: http://dx.doi.org/10.1021/ol047462s

Abstract

A novel cholaphane has been synthesized from a naturally occurring bile acid in just two steps. It has an ability to bind two fluoride ions selectively utilizing the glycolate motif in chloroform. This "inside-out" cyclodextrin analogue encapsulates fluoride through O-H···F- and C-H···F- interaction.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:21154
Deposited On:20 Nov 2010 09:02
Last Modified:02 Jun 2011 11:58

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