Chakraborty, Tushar K. ; Thippeswamy, Devasamudram ; Suresh, Vayalakkada R. ; Jayaprakash, Sarva (1997) Synthetic studies toward potent cytotoxic agent amphidinolide B : synthesis of the entire C14-C26 moiety of the top half Chemistry Letters, 26 (6). pp. 563-564. ISSN 0366-7022
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Official URL: http://www.jstage.jst.go.jp/article/cl/26/6/26_563...
Related URL: http://dx.doi.org/10.1246/cl.1997.563
Abstract
Regioselective hydroboration of a 4-methyl-2-alkene, oxidation of the resulting mixture of isomeric alcohols, and finally diastereoselective reduction of the ketone are the key steps in the stereoselective synthesis of C19-C26 fragment of amphidinolide B which was coupled with the C14-C18 fragment leading to the first synthesis of the entire C14-C26 moiety of this important molecule.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Chemical Society of Japan. |
| ID Code: | 20619 |
| Deposited On: | 20 Nov 2010 13:51 |
| Last Modified: | 23 May 2011 03:52 |
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