Chakraborty, Tushar Kanti ; Tapadar, Subhasish ; Roy, Saumya (2005) Synthesis of 3,5-dihydroxy-2,4-dimethylheptanoic acid δ-lactone in enantiomerically pure form Arkivoc, 2005 (iii). pp. 170-178. ISSN 1424-6376
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Official URL: http://www.arkat-usa.org/get-file/19923/
Abstract
Radical-mediated opening of a chiral trisubstituted epoxy alcohol using cp2TiCl was followed by diastereoselective reduction of the resulting olefinic diol to build all the chiral centers of 3,5- dihydroxy-2,4-dimethylheptanoic acid δ-lactone 1 in their desired stereochemistries leading to the total synthesis of this highly substituted δ-lactone.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Arkat USA Inc. |
| Keywords: | 3,5-Dihydroxy-2,4-dimethylheptanoic Acid; δ-lactone; Sharpless Kinetic Resolution; Epoxide Opening; 2-methyl-1, 3-diol |
| ID Code: | 20549 |
| Deposited On: | 20 Nov 2010 14:19 |
| Last Modified: | 17 May 2016 04:51 |
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