Total synthesis of stevastelin B3

Chakraborty, Tushar Kanti ; Ghosh, Subhash ; Laxman, Pasunoori ; Dutta, Shantanu ; Samanta, Rajarshi (2005) Total synthesis of stevastelin B3 Tetrahedron Letters, 46 (33). pp. 5447-5450. ISSN 0040-4039

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The total synthesis of stevastelin B3 was achieved using, as a key step, a method developed by us for the synthesis of 2-methyl-1,3-diols by Ti(III)-mediated diastereo- and regioselective opening of trisubstituted 2,3-epoxy alcohols, to carry out the stereoselective construction of its propionate-derived fatty acid segment.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Stevastelins; Epoxide Opening; 2-Methyl-1; 3-diol; Immunosuppressants; Depsipeptide
ID Code:20532
Deposited On:20 Nov 2010 14:22
Last Modified:20 Nov 2010 14:22

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