Chakraborty, Tushar Kanti ; Samanta, Rajarshi ; Das, Sanjib (2006) Radical-mediated opening of 2,3-epoxy alcohols using Cp2TiCl: stereoselective construction of quaternary chiral centers Journal of Organic Chemistry, 71 (8). pp. 3321-3324. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo0600961
Related URL: http://dx.doi.org/10.1021/jo0600961
Abstract
Radical-mediated opening of chiral 2,3-epoxy alcohols regioselectively at the 2-position using Cp2TiCl and trapping the intermediate radical with methyl acrylate and acrylonitrile led to the stereoselective formation of tetrasubstituted chiral centers.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 20523 |
| Deposited On: | 20 Nov 2010 14:22 |
| Last Modified: | 20 Nov 2010 14:22 |
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