Total synthesis of (+)-conagenin

Chakraborty, Tushar Kanti ; Sudhakar, Gangarajula (2006) Total synthesis of (+)-conagenin Tetrahedron Letters, 47 (33). pp. 5847-5849. ISSN 0040-4039

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The total synthesis of the immunomodulator, (+)-conagenin was achieved using, as a key step, a method developed by us for the synthesis of 2-methyl-1,3-diols via Ti(III)-mediated diastereo- and regioselective opening of trisubstituted 2,3-epoxy alcohols, to carry out the stereoselective construction of its pentanoic acid segment.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Conagenin; Epoxide Opening; 2-Methyl-1; 3-diol; Immunomodulator
ID Code:20505
Deposited On:20 Nov 2010 14:24
Last Modified:20 Nov 2010 14:24

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