Chakraborty, Tushar Kanti ; Goswami, Rajib Kumar (2007) Studies directed towards the total synthesis of botcinic acid, the revised structure of botcinolide: synthesis of the highly substituted tetrahydropyran moiety Tetrahedron Letters, 48 (37). pp. 6463-6465. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2007.07.068
Abstract
Synthesis of the highly substituted polyoxygenated tetrahydropyran ring of botcinic acid, the revised structure of botcinolide is achieved using, as key steps, a highly stereoselective aldol reaction of the titanium enolate from a lactate-derived chiral ketone and a stereoselective dihydroxylation.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Botcinolides; Botcinic Acid; Dihydroxylation; Aldol Reaction; Sharpless Epoxidation |
| ID Code: | 20478 |
| Deposited On: | 20 Nov 2010 14:27 |
| Last Modified: | 20 Nov 2010 14:27 |
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