Synthetic studies on terpenoids. part 21. Synthesis of a few perhydro-phenanthrene derivatives related to cheilanthatriol and its degradation products

Venkateswaran, Ramanathapuram V. ; Mukherjee, Debabrata ; Dutta, Phanindra Chandra (1981) Synthetic studies on terpenoids. part 21. Synthesis of a few perhydro-phenanthrene derivatives related to cheilanthatriol and its degradation products Journal of the Chemical Society Perkin Transactions 1 . pp. 1603-1606. ISSN 1472-7781

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Official URL: http://www.rsc.org/publishing/journals/P1/article....

Related URL: http://dx.doi.org/10.1039/P19810001603

Abstract

Stereospecific syntheses of 10α-hydroxy-1,1,4aβ,8aβ-tetramethyl-trans-transoid-trans-2,3,4,a,4b,5,7,8,8a,9,-10,10a-dodecahydrophenanthren-6(1H)-one (9) and 1,1,4aβ,8aβ-tetramethyl-8β-(3-methylpentanoyl)-2,3,4,4a,-4b,5,7,8,8a,9-decahydrophenanthren-6(1H)-one (15), potential intermediates for cheilanthatriol, are described. A few related transformations examined during these studies are discussed.

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