Magnetic behaviour of spin-mixed iron(III) porphyrins

Mitra, Samaresh ; Marathe, V. R. ; Birdy, Roshun (1983) Magnetic behaviour of spin-mixed iron(III) porphyrins Chemical Physics Letters, 96 (1). pp. 103-107. ISSN 0009-2614

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Detailed average magnetic susceptibility (295-4.2 K) and average magnetisation (20-2 K, 50-10 kOe) are reported for two novel spin-mixed iron(III) porphyrins, namely Fe(TPP)ClO4 and Fe(OEP)ClO4. The results confirm an S = 3/2 ground state substantially spin-mixed with a low-lying S = 5/2 state, but do not agree in detail with the crystal-field model of Maltempo.

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ID Code:20093
Deposited On:20 Nov 2010 15:02
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