Electron spin resonance studies of distorted octahedral ruthenium(III) species

Bhattacharya, Samaresh ; Chakravorty, Animesh (1985) Electron spin resonance studies of distorted octahedral ruthenium(III) species Proceedings of the Indian Academy of Sciences - Chemical Sciences, 95 (1-2). pp. 159-167. ISSN 0253-4134

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Official URL: http://www.ias.ac.in/j_archive/chemsci/95/1/159-16...

Related URL: http://dx.doi.org/10.1007/BF02839725

Abstract

The g-tensor theory of low-spin d5 configuration in octahedral fields having axial (tetragonal or trigonal) and rhombic distorsions is summarised. Illustrations taken from literature concern the following ruthenium(III) species: Ru(H2O) 6 3+(trigonal), Ru(bpy) 3 3+ (trigonal), the Creutz-Taube cation (axial + rhombic) and RuCl2(HL) (L) (axial + rhombic: HL = isonitrosoketone). The rationalisation of distorsion parameters in terms of bonding is considered.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
Keywords:Ruthenium; Distorsion Parameters; Electron Spin Resonance
ID Code:2005
Deposited On:08 Oct 2010 09:34
Last Modified:16 May 2016 13:02

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