Bhaduri, Sumit ; Sharma, Krishna ; Jones, Peter G. ; Erdbrügger, Cristina Freire (1987) Platinum-silver clusters: synthesis and crystal structure of [Pt3Ag(μ-CO)3(PPh3)5]ClO4 · 2H2O Journal of Organometallic Chemistry, 326 (1). C46-C48. ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002232...
Related URL: http://dx.doi.org/10.1016/0022-328X(87)80142-0
Abstract
Reaction of [NBu4]2[Pt12(CO)24] with [Ag(PPh3)4]ClO4 and PPh3 leads to two isolable platinum-silver clusters; the title complex was characterised by single crystal X-ray diffraction. the Pt3Ag core is tetrahedral; one Pt atom is seven-coordinated, the other two are six-coordinate.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 1997 |
| Deposited On: | 08 Oct 2010 09:35 |
| Last Modified: | 18 Jan 2011 04:54 |
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