13C NMR studies on M(CN)5Xn- complexes

Narayanan, B. A. ; Manoharan, P. T. (1978) 13C NMR studies on M(CN)5Xn- complexes Journal of Inorganic and Nuclear Chemistry, 40 (12). pp. 1993-1996. ISSN 0022-1902

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...

Related URL: http://dx.doi.org/10.1016/0022-1902(78)80188-2


The 13C chemical shifts for a variety of M(CN)5Xn- complexes are reported. These chemical shifts correlate extremely well with the M---C and C---N stretching frequencies and Mossbauer isomer shifts and quadrupole splitting values for the iron complexes. However, the calculated shielding constants do not correlate well with the observed shifts.

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ID Code:19909
Deposited On:22 Nov 2010 11:41
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