Isolation and X-ray structure determination of Ru4(CO)12(C6H6O), a precatalyst for the transfer hydrogenation of cyclohex-1-en-2-one

Basu, Amithaba ; Bhaduri, Sumit ; Sharma, Krishna ; Jones, Peter G. (1987) Isolation and X-ray structure determination of Ru4(CO)12(C6H6O), a precatalyst for the transfer hydrogenation of cyclohex-1-en-2-one Journal of Organometallic Chemistry, 328 (3). C34-C36. ISSN 0022-328X

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002232...

Related URL: http://dx.doi.org/10.1016/0022-328X(87)80261-9

Abstract

Ru4(CO)12(C6H6O) (1) and Ru3(CO)10(C6H8O) (2) have been obtained from the reaction of Ru3(CO)12 with cyclohex-1-en-2-one; 1 has been characterized by an X-ray structure determination. Both 1 and 2 have been found to be active precatalysts for the transfer hydrogenation of cyclohex-1-en-2-one.

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