Mathur, Pradeep ; Chatterjee, Saurav ; Das, Atanu ; Lahiri, Goutam K. ; Maji, Somnath ; Mobin, Shaikh M. (2007) Synthesis, structure and electrochemistry of CO incorporated diruthenium metallacyclic compounds [Ru2(CO)6{μ-η1:η1:η2:η2-1,4-Fc2C5H2O}] and [Ru2(CO)6{μ-η1:η1:η2:η2-1,5-Fc2C5H2O}] Journal of Organometallic Chemistry, 692 (7). pp. 1601-1607. ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...
Related URL: http://dx.doi.org/10.1016/j.jorganchem.2006.12.017
Abstract
Ferrocenyl substituted ruthenium metallacyclic compounds, [Ru2(CO)6{μ-η1:η1:η2:η2-1,4-Fc2C5H2O}] (1) and [Ru2(CO)6{μ-η1:η1:η2:η2-1,5-Fc2C5H2O}] (2) have been synthesized and structurally characterized. Electrochemical studies for 1 and 2 and the respective quinone derivatives 3 and 4 show weak to no electrochemical coupling at the mixed-valent intermediate state which is dependent on the complex frameworks.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Ferrocene; Ruthenium; Metallacycle; Electrochemistry |
| ID Code: | 19067 |
| Deposited On: | 25 Nov 2010 14:25 |
| Last Modified: | 06 Jun 2011 04:31 |
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