Unprecedented migration of a methyl group in 2-(2′,6′-dimethylphenylazo)-4-Methylphenol mediated by ruthenium

Nag, Sumon ; Gupta, Parna ; Butcher, Ray. J. ; Bhattacharya, Samaresh (2004) Unprecedented migration of a methyl group in 2-(2′,6′-dimethylphenylazo)-4-Methylphenol mediated by ruthenium Inorganic Chemistry, 43 (16). pp. 4814-4816. ISSN 0020-1669

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic049494h

Related URL: http://dx.doi.org/10.1021/ic049494h

Abstract

An unprecedented chemical transformation of 2-(2′,6′-dimethylphenylazo)-4-methylphenol has been observed upon its reaction with [Ru(PPh3)2(CO)2Cl2] whereby the methyl group at the 2′ position migrates to the 4′ or 6′ position.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:1892
Deposited On:08 Oct 2010 11:40
Last Modified:21 Jan 2011 10:39

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