Unusual transformation of trialkylamines mediated by platinum

Halder, Sarmistha ; Drew, Michael G. B. ; Bhattacharya, Samaresh (2006) Unusual transformation of trialkylamines mediated by platinum Organometallics, 25 (26). pp. 5969-5972. ISSN 0276-7333

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Official URL: http://pubs.acs.org/doi/abs/10.1021/om0607494

Related URL: http://dx.doi.org/10.1021/om0607494

Abstract

An interesting chemical transformation of trialkylamines has taken place during the reaction of 2-(2',6'-dimethylphenylazo)-4-methylphenol (1) with K2[PtCl4] in refluxing methanol in the presence of trialkylamines, leading to the formation of organoplatinum complexes (2 and 3), where ligand 1 is coordinated as a bidentate N,O donor and the transformed trialkylamines are coordinated as bidentate C,N donors.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:1878
Deposited On:08 Oct 2010 11:52
Last Modified:21 Jan 2011 10:02

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