The dynamics of the formation of S2+ from CS2 by electron impact

Nagesha, K. ; Bapat, Bhas ; Marathe, V. R. ; Krishnakumar, E. (1991) The dynamics of the formation of S2+ from CS2 by electron impact Chemical Physics Letters, 230 (3). pp. 283-289. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(94)01161-3

Abstract

The dynamics of the formation of S2+ from CS2 by electron impact has been investigated by ion kinetic energy spectrometry and ab initio quantum chemical calculations on the CS2+ and CS22+ ions. The results show that S2+ is formed through a sequential process in which some of the linear CS2+ or CS22+ ions formed initially undergo a geometric change to a bent shape before dissociating to give S2+ ions.

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Deposited On:17 Nov 2010 13:12
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