Allene transfer reactions: a new synthesis of terminal allenes

Baldwin, Jack E. ; Adlington, Robert M. ; Basak, Amit (1984) Allene transfer reactions: a new synthesis of terminal allenes Journal of the Chemical Society, Chemical Communications (19). pp. 1284-1285. ISSN 0022-4936

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Official URL: http://www.rsc.org/publishing/journals/C3/article....

Related URL: http://dx.doi.org/10.1039/C39840001284

Abstract

Alkyl radicals, produced from alkyl bromides and iodides, react smoothly with triphenylprop-2-ynylstannane to provide terminal allenes; this new reaction has been applied to a simple and stereospecific synthesis of the naturally occurring allenic amino-acid, S-2-aminohexa-4,5-dienoic acid.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:1795
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Last Modified:13 Jan 2011 12:35

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