N.M.R. and I.R. studies of 1, 1, 1 trifluoroacetone in proton donor solvents

Khetrapal, C. L. ; Dhingra, M. M. ; Kartha, V. B. (1967) N.M.R. and I.R. studies of 1, 1, 1 trifluoroacetone in proton donor solvents Proceedings of the Indian Academy of Sciences, Section A, 66 (4). pp. 196-200. ISSN 0370-0089

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Official URL: http://www.ias.ac.in/j_archive/proca/66/4/196-200/...

Related URL: http://dx.doi.org/10.1007/BF03050736

Abstract

Interactions of 1, 1, 1 trifluoroacetone with proton donor solvents of the type RH [where R=HO, CH3S, CH3CH2CH2CH2S, CH3O, (CH3)2N, (C2H5)2N] have been investigated using NMR and infra-red techniques. Evidence of the formation of addition products of the type CF3.C(OH)R.CH3 where OH group is hydrogen-bonded with the fluorine of the CF3group has been obtained.

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