Transition dipole moment and intensity measurements of the a2ν2 ← sν2 hot band of 14NH3

Singh, Kuldip ; D'Cunha, Romola ; Kartha, V. B. (1988) Transition dipole moment and intensity measurements of the a2ν2 ← sν2 hot band of 14NH3 Journal of Molecular Spectroscopy, 129 (2). pp. 307-313. ISSN 0022-2852

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Official URL: http://dx.doi.org//10.1016/0022-2852(88)90037-9

Related URL: http://dx.doi.org/10.1016/0022-2852(88)90037-9

Abstract

Intensities of more than 30 vibration-rotation lines in the P-, Q-, and R-branch regions of the a2ν2 ← sν2 hot band of 14NH3 have been measured using a tunable diode laser operating in the region 860-1040 cm-1. For several of the transitions, measurements have been made both by the fast direct method and also by the equivalent width method. From the measured data a value of 0.274(5) has been derived for the transition dipole moment of the (1s|μ|2a)right-pointing angle bracket hot band. N2-broadening coefficients are also reported for a few selected transitions.

Item Type:Article
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