Krishnamurthy, Setharampattu S. ; Soundararajan, Sundaresa (1969) Charge distribution in and dipole moments of some aliphatic alcohols Journal of Physical Chemistry, 73 (12). pp. 4036-4039. ISSN 0022-3654
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Official URL: http://pubs.acs.org/doi/abs/10.1021/j100846a002
Related URL: http://dx.doi.org/10.1021/j100846a002
Abstract
Using the treatment of Smith, et al.,1 charge distributions in several aliphatic alcohols and consequently their dipole moments have been evaluated. The dipole moments of trichloroethanol (2.04 D) and 1,3-dichloropropan-2-ol (2.11 D) have been measured in benzene solution at 35°. The results of evaluation and measurements are interpreted in terms of the occurrence of intramolecular interaction between the hydroxyl hydrogen and an acceptor atom X (halogen or oxygen) at the β-carbon atom.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 17850 |
| Deposited On: | 16 Nov 2010 12:36 |
| Last Modified: | 08 Jun 2011 07:20 |
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