Balakrishna, Maravanji S. ; Krishnamurthy, Setharampattu S. ; Murugavel, Ramaswamy ; Nethaji, Munirathinam ; Mathews, Irimpan I. (1993) Organometallic chemistry of diphosphazanes. Part 7. Platinum(II), palladium-(o), -(I) and -(II) complexes of RN[P(OPh)2]2(R = Me or Ph) Journal of the Chemical Society, Dalton Transactions (3). pp. 477-482. ISSN 0300-9246
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1993...
Related URL: http://dx.doi.org/10.1039/DT9930000477
Abstract
The reactions of [MCl2(cod)](M = Pd or Pt, cod = cycloocta-1,5-diene) with RN[P(OPh)2]2[R = Me (L1) or Ph (L2)] afford the chelate complexes [MCl2L1] and [MCl2L2]. The dinuclear palladium(O) complex, [Pd2L13] has been synthesized by starting from [Pd2(dba)3](dba = dibenzylideneacetone). Redox condensation of [Pd2(dba)3] and [PdCl2(PhCN)2] in the presence of the diphosphazane ligands gives the dinuclear palladium(I) complexes [Pd2Cl2L12] and [Pd2Cl2L22]. The structures of the complexes have been deduced from 1H and 31P NMR spectroscopic data. Single-crystal X-ray diffraction studies confirm the structures of [Pd2L13] and [Pd2Cl2L22].
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 17804 |
| Deposited On: | 16 Nov 2010 12:40 |
| Last Modified: | 08 Jun 2011 06:57 |
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