Kamalesh Babu, R. P. ; Krishnamurthy, S. S. (1994) Organometallic chemistry of diphosphazanes. Part IX: Syntheses and spectroscopic studies of molybdenum and tungsten tetracarbonyl complexes of unsymmetrical diphosphazanes Proceedings of the Indian Academy of Sciences - Chemical Sciences, 106 (1). pp. 37-43. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/106/1/37-43...
Related URL: http://dx.doi.org/10.1007/BF02867591
Abstract
The unsymmetrical diphosphazanes X2PN(Pri)PYY'(1a-1h) {X=Ph, YY'=O2 C6H4 (1a) or YY'=O2C12H8 (1b); X=Ph, Y=Ph, Y'=OC6H4Me-4 (1c), OC6H4Br-4 (1d), OC6H3Me2-3,5 (1e), OC5H4N-2 (1f), N2C3HMe2-3,5 (1g) or Cl (1h)} react with [M(CO)4(NHC5H10)2] (M=Mo, W) to yield thecis-chelate complexes [M(CO)4{X2PN(Pri) PYY'}] {M=Mo (2a-2h); M=W (3f,3g)}. These complexes have been characterized by 1H, 31P and13C NMR and IR spectroscopic studies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Unsymmetrical Diphosphazane Ligands; Group 6 Carbonyl Complexes |
| ID Code: | 17772 |
| Deposited On: | 16 Nov 2010 12:43 |
| Last Modified: | 17 May 2016 02:24 |
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