Chandrashekar, T. K. ; Krishnan, V. (1981) Coordinative interaction of morpholine with divalent metallo tetraphenyl porphyrins Journal of Inorganic and Nuclear Chemistry, 43 (12). pp. 3287-3290. ISSN 0022-1902
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...
Related URL: http://dx.doi.org/10.1016/0022-1902(81)80104-2
Abstract
The formation of axially coordinated morpholine (morph) complexes of MTPP, (M = Co, Ni, Cu and Zn) has been studied. Morpholine coordinates through imino nitrogen to the metal ions with the retainment of equatorial conformation. The presence of spin-free, NiTPP (morph), (S = 1) and an equilibrium mixture of CoTPP and an oxygen adduct of CoTPP (morph) in solution have been observed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 17289 |
| Deposited On: | 16 Nov 2010 08:02 |
| Last Modified: | 27 May 2011 11:57 |
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