Influence of cations on zinc(II) incorporation into crown porphyrins

Thanabal, V. ; Krishnan, V. (1983) Influence of cations on zinc(II) incorporation into crown porphyrins Polyhedron, 2 (6). pp. 505-507. ISSN 0277-5387

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S02775...

Related URL: http://dx.doi.org/10.1016/S0277-5387(00)87102-8

Abstract

The decrease in rate constants of Zn(II) incorporation into fully and partially benzo-15-crown-5 meso substituted porphyrins in the presence of cations has been explained on the basis of cation complexation ability of the crown ether cavities rather than steric effects.

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ID Code:17264
Deposited On:16 Nov 2010 08:05
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