Kar, Moumita ; Basak, Amit ; Bhattacharjee, Manish (2005) Photoisomerization as a trigger for Bergman cyclization: synthesis and reactivity of azoenediynes Bioorganic & Medicinal Chemistry Letters, 15 (24). pp. 5392-5396. ISSN 0960-894X
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/S09608...
Related URL: http://dx.doi.org/10.1016/j.bmcl.2005.09.005
Abstract
Cyclic enediynes 1a and 2a containing stable E-azo moiety (azoenediynes) have been synthesized. These compounds upon irradiation with long wavelength UV isomerize to the Z-compounds 1b and 2b, which can be thermally reisomerized to the Z compounds. Reactivity studies toward BC using DSC predictably indicate higher reactivity for the Z-isomers. Our studies may provide a novel way to modulate the reactivity of enediynes under thermal or photochemical conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Photoisomerization; Azoenediyne; Triggering; Bergman Cyclization; Coupling |
| ID Code: | 1717 |
| Deposited On: | 05 Oct 2010 12:05 |
| Last Modified: | 13 Jan 2011 09:59 |
Repository Staff Only: item control page
