Phenylthiomethylstannylation of silyl enol ethers and silyl dienol ethers

Iqbal, Javed (1989) Phenylthiomethylstannylation of silyl enol ethers and silyl dienol ethers Tetrahedron Letters, 30 (2). pp. 239-242. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S0040-...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)95170-0

Abstract

Silyl enol ethers (2) react with tributyl [(phenylthio) chloromethyl] stannane (1) in the presence of Zinc bromide to give β-phenylthiomethylstannyl ketones (3) in good yields. Silyl dienol ethers (4) mainly give products (5) due to γ-attack, under these conditions.

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