Cobalt catalysed allylic and benzylic oxidations with dioxygen in the presence of ethyl 2-oxocyclopentanecarboxylate

Punniyamurthy, T. ; Iqbal, Javed (1994) Cobalt catalysed allylic and benzylic oxidations with dioxygen in the presence of ethyl 2-oxocyclopentanecarboxylate Tetrahedron Letters, 35 (23). pp. 4003-4006. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)76725-6

Abstract

An efficient allylic and benzylic oxidation of various cyclic alkenes and benzylic compounds respectively can be achieved with dioxygen in the presence of ethyl 2-oxocyclopentanecarboxylate 2 and catalytic amount of cobalt(II) Schiff's base complex 1.

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