Madhava Reddy, M. ; Punniyamurthy, T. ; Iqbal, Javed (1995) Cobalt catalyzed oxidation of cyclic alkenes with molecular oxygen: allylic oxidation versus double bond attack Tetrahedron Letters, 36 (1). pp. 159-162. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004040...
Related URL: http://dx.doi.org/10.1016/0040-4039(94)02200-U
Abstract
Cobalt(II) Schiff's base complex 1 and 2 exhibit a remarkable chemoselectivity during oxidation of cyclic alkenes with molecular oxygen in the presence of 2- methylpropanal. Catalyst 1 encourages the oxidation of double bond to give epoxide as the major product whereas catalyst 2 promotes mainly the allylic oxidation leading to allylic alcohols or enones.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 17002 |
| Deposited On: | 16 Nov 2010 13:10 |
| Last Modified: | 17 Feb 2011 05:14 |
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