Synthesis and thermal reactivity of a novel macrocyclic enediyne and its copper(II) complex

Basak, Amit ; Shain, Jagadish Chandra (1998) Synthesis and thermal reactivity of a novel macrocyclic enediyne and its copper(II) complex Tetrahedron Letters, 39 (19). pp. 3029-3030. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(98)00325-6

Abstract

A novel 24-membered tetraazaenediyne and its copper(II) complex have been synthesized via a Pd(0)-catalysed macrocyclization route. DSC measurements revealed a lowering of onset temperature for Bergman Cyclization upon complexation.

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