A novel investigation of vapor-phase charge-transfer complexes of halogens with n-donors by electron energy loss spectroscopy

Vishnu Kamath, P. ; Hegde, M. S. ; Rao, C. N. R. (1986) A novel investigation of vapor-phase charge-transfer complexes of halogens with n-donors by electron energy loss spectroscopy Journal of Physical Chemistry, 90 (10). pp. 1990-1992. ISSN 0022-3654

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Official URL: http://pubs.acs.org/doi/abs/10.1021/j100401a003

Related URL: http://dx.doi.org/10.1021/j100401a003

Abstract

Complexes of I2 with diethyl ether and triethylamine and of Br, with diethyl ether have been investigated in the vapor phase for the first time by employing electron energy loss spectroscopy. Besides the CT bands, blue-shifted vacuum-UV bands of the halogens have been assigned; the amine-I, system appears to exhibit two CT bands,associated with two different excited states of the complex.

Item Type:Article
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