Diels-Alder reactions are faster in water than in ionic liquids at room temperature

Tiwari, Shraeddha ; Anil Kumar, (2006) Diels-Alder reactions are faster in water than in ionic liquids at room temperature Angewandte Chemie International Edition, 45 (29). pp. 4824-4825. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...

Related URL: http://dx.doi.org/10.1002/ange.200600426

Abstract

Nobody does it better: A comparative study indicates that water, rather than room-temperature ionic liquids (RTILs), is still the solvent of choice for accelerating Diels-Alder reactions. Both the hydrogen-bonding ability and the viscosity of the solvent are thought to play a role.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Diels-Alder Reaction; Ionic Liquids; Kinetics; Solvent Effects; Viscosity
ID Code:1601
Deposited On:05 Oct 2010 12:13
Last Modified:12 May 2011 05:35

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