Charge transfer in chevrel phases

Yashonath, S. ; Hegde, M. S. ; Sarode, P. R. ; Rao, C. N. R. ; Umarji, A. M. ; Subba Rao, G. V. (1981) Charge transfer in chevrel phases Solid State Communications, 37 (4). pp. 325-327. ISSN 0038-1098

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Chemical shifts of Mo K-absorption edge and Mo core level binding energies in Ax Mo6 Ch8 (Ch = S, Se, Te) Chevrel phases show clear evidence for charge transfer from the A element to the Mo6 cluster. The chemical shifts vary linearly with the intercluster Mo-Mo distance as well as the rhombohedral parameter.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:15868
Deposited On:13 Nov 2010 12:24
Last Modified:03 Jun 2011 09:34

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