Mehta, Barun K. ; Ila, Hiriyakkanavar ; Junjappa, Hiriyakkanavar (1995) Highly chemoselective and stereoselective conjugate addition of benzyl copper reagents to α-oxoketene dithioacetals Tetrahedron Letters, 36 (11). pp. 1925-1928. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004040...
Related URL: http://dx.doi.org/10.1016/0040-4039(95)00158-9
Abstract
Benzyl copper reagents derived by transmetallation between benzylmagnesium chloride and Cu(I) species are shown to undergo conjugate addition - elimination with acyclic and cyclic α-oxoketene dithioacetals to afford the corresponding β-benzyl vinylogous thiolesters in highly stereo- and chemoselective manner.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 15325 |
| Deposited On: | 13 Nov 2010 12:56 |
| Last Modified: | 22 Feb 2011 08:29 |
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