Regioselective synthesis of substituted 1-methyl- and 2-methylnaphthalenes

Yadav, K. Mallik ; Mohanta, Pramod K. ; Ila, Hiriyakkanavar ; Junjappa, Hiriyakkanavar (1996) Regioselective synthesis of substituted 1-methyl- and 2-methylnaphthalenes Tetrahedron, 52 (44). pp. 14049-14056. ISSN 0040-4020

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004040...

Related URL: http://dx.doi.org/10.1016/0040-4020(96)80832-5

Abstract

Regiospecifically substituted 1-methyl- and 2-methylnaphthalenes, 5-methyl- and 6-methyl-1,2,3,4-tetrahydroanthracenes have been synthesized in good yields through 1,2- addition of the corresponding α-lithio-o-or m-xylenes onto α-oxoketene dithioacetals or their dihydro derivatives followed by cyclodehydration of the resulting carbinols in the presence of borontrifluoride etherate.

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